Soap scum or lime soap is the white solid composed of

calcium stearate Calcium stearate is a carboxylate salt of calcium, classified as a calcium soap. The salt is a component of some lubricants, surfactants, as well as many foodstuffs. It is a white waxy powder. Production and occurrence Calcium stearate is pro ...

magnesium stearate Magnesium stearate is the chemical compound with the formula . It is a soap, consisting of salt containing two equivalents of stearate (the anion of stearic acid) and one magnesium cation (Mg2+). Magnesium stearate is a white, water-insoluble pow ...

, and similar

alkaline earth metal The alkaline earth metals are six chemical elements in group 2 of the periodic table. They are beryllium (Be), magnesium (Mg), calcium (Ca), strontium (Sr), barium (Ba), and radium (Ra).. The elements have very similar properties: they are all ...

derivatives of fatty acids. These materials result from the addition of

soap Soap is a salt of a fatty acid used in a variety of cleansing and lubricating products. In a domestic setting, soaps are surfactants usually used for washing, bathing, and other types of housekeeping. In industrial settings, soaps are use ...

and other

anionic surfactant Surfactants are chemical compounds that decrease the surface tension between two liquids, between a gas and a liquid, or interfacial tension between a liquid and a solid. Surfactants may act as detergents, wetting agents, emulsifiers, foaming ...

s to

hard water Hard water is water that has high mineral content (in contrast with "soft water"). Hard water is formed when water percolates through deposits of limestone, chalk or gypsum, which are largely made up of calcium and magnesium carbonates, bicarbo ...

. Hard water contains

calcium Calcium is a chemical element with the symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar t ...

and

magnesium Magnesium is a chemical element with the symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 of the periodic ta ...

ions, which react with the surfactant anion to give these metallic or lime soaps.{{Ullmann, author=Angelo Nora, Alfred Szczepanek, Gunther Koenen, title=Metallic Soaps, year=2005, doi=10.1002/14356007.a16_361 :2 C₁₇H₃₅COO⁻Na⁺ + Ca²⁺ → (C₁₇H₃₅COO)₂Ca + 2 Na⁺ In this reaction, the

sodium Sodium is a chemical element with the symbol Na (from Latin ''natrium'') and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 of the periodic table. Its only stable ...

cation in soap is replaced by calcium to form

. Lime soaps build deposits on fibres, washing machines, and sinks. Synthetic surfactants are less susceptible to the effects of hard water. Most detergents contain

builders Builder may refer to: * Construction worker, who specializes in building work * Carpenter, a skilled craftsman who works with wood * General contractor, that specializes in building work ** Subcontractor * Builder (detergent), a component of mode ...

that prevent the formation of lime soaps.

References

Water treatment Soaps

See also

References